XPS STUDY OF POLYMER-CHAIN CONFORMATION IN AMORPHOUS AND CRYSTALLINE POLY(ETHYLENE-TEREPHTHALATE) SAMPLES

被引：20
作者：
BOULANGER, P
PIREAUX, JJ
VERBIST, JJ
DELHALLE, J
机构：
[1] FAC UNIV NOTRE DAME PAIX,INTERDISCIPLINAIRE SPECT ELECTR LAB,61 RUE BRUXELLES,B-5000 NAMUR,BELGIUM
[2] FAC UNIV NOTRE DAME PAIX,CHIM THEOR APPL LAB,B-5000 NAMUR,BELGIUM
来源：
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 1993年 / 63卷 / 01期
关键词：
D O I：
10.1016/0368-2048(93)85014-C
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
The chain conformations at the surface of poly(ethylene terephthalate) (PET) with amorphous and crystalline (bioriented film) morphologies are characterized by means of IR-ATR spectroscopy. Experimental XPS valence bands are analysed with the help of theoretically simulated XPS valence band spectra for model molecules of PET chains in different conformations. The differences observed in the experimental spectra of the samples are tentatively interpreted as being of conformational origin.
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页码：53 / 73
页数：21
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