ASYMMETRIC HYDROCYANATION OF 3-PHENOXYBENZALDEHYDE CATALYZED BY POLY(CINCHONA ALKALOID-CO-ACRYLONITRILE)S

被引：24

作者：

DANDA, H ^{[1
]}

CHINO, K ^{[1
]}

WAKE, S ^{[1
]}

机构：

[1] SUMITOMO CHEM CO LTD, EHIME RES LAB, NIIHAMA, EHIME 792, JAPAN

来源：

CHEMISTRY LETTERS | 1991年 / 04期

关键词：

D O I：

10.1246/cl.1991.731

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Asymmetric addition of hydrogen cyanide to 3-phenoxybenzaldehyde catalyzed by poly(quinidine-co-acrylonitrile) affords (S)-2-hydroxy-2-(3'-phenoxyphenyl)-acetonitrile in a moderate optical yield.

引用

页码：731 / 732

页数：2

共 8 条

[1] SYNTHESES OF DIASTEREOISOMERS OF RECENT PYRETHROIDS, FENVALERATE (S-5602) AND CYPERMETHRIN (NRDC-149) FROM (-)-3-PHENOXY-MANDELIC ACID AND DETERMINATION OF THEIR ABSOLUTE-CONFIGURATIONS [J].

AKETA, KI ;

OHNO, N ;

ITAYA, N ;

NAKAYAMA, I ;

YOSHIOKA, H .

AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1978, 42 (04) :895-896

[2]

Bredig G, 1912, BIOCHEM Z, V46, P7

[3] POLY(CINCHONA ALKALOID-CO-ACRYLONITRILE)S - NEW POLYMER CATALYSTS FOR ASYMMETRIC SYNTHESIS [J].

KOBAYASHI, N ;

IWAI, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (22) :7071-7072

[4] FUNCTIONAL POLYMERS .2. SYNTHESIS AND PROPERTIES OF NEW POLYMERIC CINCHONA ALKALOIDS [J].

KOBAYASHI, N ;

IWAI, K .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1980, 18 (01) :223-233

[5] FUNCTIONAL POLYMERS .3. ASYMMETRIC MICHAEL REACTIONS CATALYZED BY CINCHONA ALKALOID-ACRYLONITRILE CO-POLYMERS [J].

KOBAYASHI, N ;

IWAI, K .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1980, 18 (03) :923-932

[6] ASYMMETRIC ADDITION OF HYDROGEN-CYANIDE TO SUBSTITUTED BENZALDEHYDES CATALYZED BY A SYNTHETIC CYCLIC PEPTIDE, CYCLO((S)-PHENYLALANYL-(S)-HISTIDYL) [J].

KOBAYASHI, Y ;

ASADA, S ;

WATANABE, I ;

HAYASHI, H ;

MOTOO, Y ;

INOUE, S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1986, 59 (03) :893-895

[7] RECENT TOPICS IN THE CHEMISTRY OF SYNTHETIC PYRETHROIDS CONTAINING CERTAIN SECONDARY ALCOHOL MOIETIES [J].

MATSUO, T ;

NISHIOKA, T ;

HIRANO, M ;

SUZUKI, Y ;

TSUSHIMA, K ;

ITAYA, N ;

YOSHIOKA, H .

PESTICIDE SCIENCE, 1980, 11 (02) :202-218

[8] UNTERSUCHUNGEN UBER ASYMMETRISCHE SYNTHESEN .6. DER REAKTIONSMECHANISMUS UND DER STERISCHE VERLAUF DER ASYMMETRISCHEN CYANHYDRIN-SYNTHESE [J].

PRELOG, V ;

WILHELM, M .

HELVETICA CHIMICA ACTA, 1954, 37 (06) :1634-1660

← 1 →