A NEW STRUCTURE MAGNETISM RELATIONSHIP FOR FACE-SHARING TRANSITION-METAL COMPLEXES WITH D3-D3 ELECTRONIC CONFIGURATION

被引：67

作者：

NIEMANN, A

BOSSEK, U

WIEGHARDT, K

BUTZLAFF, C

TRAUTWEIN, AX

NUBER, B

机构：

[1] RUHR UNIV BOCHUM,LEHRSTUHL ANORGAN CHEM 1,UNIV STR 150,W-4630 BOCHUM 1,GERMANY

[2] MED UNIV LUBECK,INST PHYS,LUBECK,GERMANY

[3] UNIV HEIDELBERG,INST ANORGAN CHEM,W-6900 HEIDELBERG,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 03期

关键词：

D O I：

10.1002/anie.199203111

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A through-space interaction and not superexchange of the bridging ligands explains the antiferromagnetic coupling in dinuclear face-sharing octahedral complexes with d3-d3 electronic configuration. The metal-metal distance is the only relevant structural parameter for the spin-exchange coupling constants of a series of V-2(II), Cr-2(III), and Mn-2(IV) complexes.

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页码：311 / 313

页数：3

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