SYNTHESIS AND CHARACTERIZATION OF COMPLEXES OF THALLIUM(III) HALIDES WITH SUBSTITUTED IMIDAZOLES

被引：1
作者：
BERMEJO, MR
FERNANDEZ, MI
FERNANDEZ, B
GOMEZ, ME
机构：
[1] Departamento de Quimica Inorgánica, Facultade de Quimica Universidade de Santiago de Compostela, Galiza
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1992年 / 22卷 / 06期
关键词：
D O I：
10.1080/15533179208020243
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions between TlX3 (X = Cl, Br, or I) and substituted imidazoles [(2-methyl-imidazole (2-Me-Im), 2-phenyl-imidazole (2-Phen-Im), 2-ethyl-imidazole (2-Et-Im), 1,2-dimethyl-imidazole (1,2-Me2-Im) and 1-methyl-2-phenyl-imidazole (1-Me,2-Phen-Im)] in various donor-acceptor molar ratios have been studied. The complexes formed have been characterized by elemental analysis. The complexes are monomeric solids and non-electrolytes in acetonitrile. Possible structures are discussed on the basis of H-1 NMR and i.r. spectroscopy and comparison with structures in the literature.
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页码：759 / 773
页数：15
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