THE INFRARED-SPECTRA OF RHENIUM PENTAMETHYL CYCLOPENTADIENYL COMPLEXES - (N5-C5ME5)RE(CO3) AND [(N5-C5ME5)RE(CO)3X]+ (X = CL, BR, I)

被引:12
|
作者
DIAZ, G [1 ]
KLAHN, AH [1 ]
机构
[1] PONTIFICIA UNIV CATOLICA VALPARAISO, INST QUIM, VALPARAISO, CHILE
关键词
5-C5Me5)Re(CO)3; Infrared spectra Band assignments Force constants (η; (η-C5Me5)Re(CO)3X) +;
D O I
10.1080/00387019008054038
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
The IR spectra of the title compounds are recorded and an assignment of the normal modes in terms of local symmetry is suggested by comparison with those observed in analogous molecules. A set of force constants calculated for simplified models, confirms most of the. © 1990, Taylor & Francis Group, LLC. All rights reserved.
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页码:87 / 109
页数:23
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