A NOVEL CATALYTIC CYCLE FOR THE SYNTHESIS OF EPOXIDES USING SULFUR YLIDES - APPLICATION TO BASE SENSITIVE ALDEHYDES

被引：25

作者：

AGGARWAL, VK ^{[1
]}

ABDELRAHMAN, H ^{[1
]}

JONES, RVH ^{[1
]}

STANDEN, MCH ^{[1
]}

机构：

[1] ZENECA FCMO,DEPT PROC TECHNOL,GRANGEMOUTH FK3 8XG,STIRLING,SCOTLAND

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 10期

关键词：

D O I：

10.1016/0040-4039(95)00103-J

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Epoxidation of base sensitive aldehydes can be achieved by a new catalytic cycle which requires the slow addition of a diazocompound to a solution of an aldehyde containing catalytic quantities of a sulfide and catalytic quantities of rhodium acetate.

引用

页码：1731 / 1732

页数：2

共 5 条

[1] NOVEL CATALYTIC CYCLE FOR THE SYNTHESIS OF EPOXIDES FROM ALDEHYDES AND SULFUR YLIDES MEDIATED BY CATALYTIC QUANTITIES OF SULFIDES AND RH-2(OAC)(4) [J].

AGGARWAL, VK ;

ABDELRAHMAN, H ;

JONES, RVH ;

LEE, HY ;

REID, BD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (13) :5973-5974

[2] EPOXIDATION OF ALDEHYDES AND OF KETONES BY A SOLID-LIQUID TRANSFER PROCESS [J].

BORREDON, E ;

DELMAS, M ;

GASET, A .

TETRAHEDRON LETTERS, 1982, 23 (50) :5283-5286

[3] EPOXIDATION IN A SLIGHTLY HYDRATED SOLID-LIQUID MEDIUM - EFFECTS OF SULFONIUM SALT STRUCTURE ON THE REACTION [J].

BORREDON, ME ;

DELMAS, M ;

GASET, A .

TETRAHEDRON, 1987, 43 (17) :3945-3954

[4] DIMETHYLOXOSULFONIUM METHYLIDE ((CH3)2SOCH2) AND DIMETHYLSULFONIUM METHYLIDE ((CH3)2SCH2) FORMATION AND APPLICATION TO ORGANIC SYNTHESIS [J].

COREY, EJ ;

CHAYKOVSKY, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (06) :1353-+

[5] ADDITION OF DIAZOMETHANE AND SULFUR YLIDES TO THE OXO-GROUP IN DERIVATIVES OF KETOSES AND ALDOSES .1. REACTIONS OF 2,3-O-ISOPROPYLIDENE-D-GLYCERALDEHYDE [J].

HAGEN, S ;

ANTHONSEN, T ;

KILAAS, L .

TETRAHEDRON, 1979, 35 (21) :2583-2589

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