1,5-SIGMATROPIC SHIFTS OF CHLORINE IN THE CYCLOPENTADIENE RING

被引：0

作者：

MIKHAILOV, IE

DUSHENKO, GA

KISIN, AV

MUGGE, C

ZSCHUNKE, A

MINKIN, VI

机构：

[1] ROSTOV STATE UNIV,INST PHYS & ORGAN CHEM,ROSTOV NA DONU 344104,RUSSIA

[2] STATE CHEM & TECHNOL ORGANOELEMENT CPD RES INST,MOSCOW,RUSSIA

[3] HUMBOLDT UNIV BERLIN,INST ANALYT CHEM,D-10115 BERLIN,GERMANY

来源：

MENDELEEV COMMUNICATIONS | 1994年 / 03期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Intramolecular rearrangement due to successive 1,5-sigmatropic shifts of chlorine over a five-membered ring were found to occur in 5-chloro-1-alkyl-2,3,4,5-tetramethoxycarbonylcyclopentadienes with energy barriers to chlorine migration falling in the range 26.0-27.3 kcal mol-1.

引用

页码：85 / 88

页数：4

共 5 条

[1] RAPID NUCLEOPHILIC SUBSTITUTIONS ON CYCLOPENTADIENYL IODIDE AND BROMIDE [J].