LIGAND CONTROLLED CARBON-CARBON BOND FORMATION VERSUS CARBON-OXYGEN BOND-CLEAVAGE N THE NICKEL-CATALYZED ELECTROCHEMICAL REDUCTION OF ALLYL O-HALOPHENYL ETHERS

被引：0

作者：

OLIVERO, S ^{[1
]}

DUNACH, E ^{[1
]}

机构：

[1] UNIV NICE SOPHIA ANTIPOLIS,CHIM MOLEC LAB,CNRS,URA 426,PARC VALROSE,F-06108 NICE 2,FRANCE

来源：

SYNLETT | 1994年 / 07期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The electrochemical reactivity of ortho-allyloxy halobenzenes in the presence of Ni(II) complexes as catalysts is determined by the nature of the ligand. Ni(II)-Cyclam complexes catalyze a cyclization reaction, whereas with Ni(II)-bipyridine complexes, die allyl-oxygen bond is selectively cleaved.

引用

页码：531 / 533

页数：3

共 47 条

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