LIGAND CONTROLLED CARBON-CARBON BOND FORMATION VERSUS CARBON-OXYGEN BOND-CLEAVAGE N THE NICKEL-CATALYZED ELECTROCHEMICAL REDUCTION OF ALLYL O-HALOPHENYL ETHERS

被引：0
|
作者：
OLIVERO, S [1 ]
DUNACH, E [1 ]
机构：
[1] UNIV NICE SOPHIA ANTIPOLIS,CHIM MOLEC LAB,CNRS,URA 426,PARC VALROSE,F-06108 NICE 2,FRANCE
来源：
SYNLETT | 1994年 / 07期
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The electrochemical reactivity of ortho-allyloxy halobenzenes in the presence of Ni(II) complexes as catalysts is determined by the nature of the ligand. Ni(II)-Cyclam complexes catalyze a cyclization reaction, whereas with Ni(II)-bipyridine complexes, die allyl-oxygen bond is selectively cleaved.
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页码：531 / 533
页数：3
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