THE CRYSTAL AND MOLECULAR-STRUCTURE OF N,N-DIETHYLDISELENOCARBAMATOCADMIUM(II) - CADMIUM AND ZINC DIETHYLDISELENOCARBAMATES AS PRECURSORS FOR SELENIDES

被引：69
作者：
HURSTHOUSE, MB
MALIK, MA
MOTEVALLI, M
OBRIEN, P
机构：
[1] Department of Chemistry, Queen Mary and Westfield College, University of London, London El 4NS, Mile End Road
来源：
POLYHEDRON | 1992年 / 11卷 / 01期
关键词：
D O I：
10.1016/S0277-5387(00)83257-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The X-ray crystal structure of N,N-diethyldiselenocarbamatocadmium(II) has been determined and contains centrosymmetric, dimeric molecular units of [Cd2(Se2 CNEt2)4] with five-coordinated distorted square pyramidal cadmium. Preliminary studies of the pyrolysis of both cadmium and zinc diethyldiselenocarbamates show that these complexes may be useful precursors for the deposition of ZnSe and CdSe.
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页码：45 / 48
页数：4
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