REACTIONS OF NAPHTHALENEYTTERBIUM WITH BIS(CYCLOPENTADIENYL) COMPLEXES OF COBALT, NICKEL, CHROMIUM AND VANADIUM - X-RAY CRYSTAL-STRUCTURE OF THE TRIPLE-DECKER CPVC10H8VCP

被引：21

作者：

BOCHKAREV, MN ^{[1
]}

FEDUSHKIN, IL ^{[1
]}

SCHUMANN, H ^{[1
]}

LOEBEL, J ^{[1
]}

机构：

[1] TECH UNIV BERLIN,INST ANORGAN & ANALYT CHEM,W-1000 BERLIN 12,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 410卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)83005-O

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Naphthaleneytterbium, C10H8Yb(THF)3 reacts with Cp2Cr, Cp2Co, Cp2Ni, and Cp2V in THF to give Cp2Yb. In the case of the reaction of C10H8Yb(THF)3 with Cp2V, vanadium-containing intermediates could be isolated. One of them, CpVC10H8VCp, has been characterized by X-ray differaction. The crystals are monoclinic, space group P2(1)/n, with a 907.0(5), b 798.8(3), c 1080.8(5) pm, beta 105.21(4)-degrees; Z = 2. The structure was refined to R = 0.0288 for 1131 observed reflections (F(o) > 4-sigma(F(o))).

引用

页码：321 / 326

页数：6

共 14 条

[1]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV, p[99, 149]

[2] SYNTHESIS AND REACTIVITY OF NAPHTHALENE COMPLEXES OF YTTERBIUM [J].

BOCHKAREV, MN ;

TRIFONOV, AA ;

FEDOROVA, EA ;

EMELYANOVA, NS ;

BASALGINA, TA ;

KALININA, GS ;

RAZUVAEV, GA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 372 (02) :217-224

[3] TRANSITION-METAL ORGANOMETALLIC COMPOUNDS .8. ARENE EXCHANGE-REACTIONS OF BIS(NAPHTHALENE)CHROMIUM [J].

BUSH, BF ;

LYNCH, VM ;

LAGOWSKI, JJ .

ORGANOMETALLICS, 1987, 6 (06) :1267-1275

[4] THE 1ST TRIPLE-DECKER SANDWICH WITH A BRIDGING BENZENE-RING [J].

DUFF, AW ;

JONAS, K ;

GODDARD, R ;

KRAUS, HJ ;

KRUGER, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (16) :5479-5480

[5]

EREMENKO IL, 1983, B ACAD SCI USSR CH, P2545

[6]

JOHNSON CK, 1965, ORNL3794 REP

[7]

JONAS K, 1986, ANGEW CHEM, V98, P904

[8] TRIS(TETRACARBONYLCOBALT)TETRAKIS(TETRAHYDROFURAN)ERBIUM [J].

MARIANELLI, RS ;

DURNEY, MT .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1971, 32 (02) :C41-+

[9] SYNTHESIS AND MOLECULAR-STRUCTURE OF LANTHANUM TRIS[CYCLOPENTADIENYLMOLYBDENOTRICARBONYLATE] TETRAHYDROFURANATE, (THF)5LA[CPMO(CO)3]3.THF [J].

PASYNSKII, AA ;

EREMENKO, IL ;

SULEIMANOV, GZ ;

NURIEV, YA ;

BELETSKAYA, IP ;

SHKLOVER, VE ;

STRUCHKOV, YT .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 266 (01) :45-52

[10]

RADKOV YF, 1988, METALLOORG KHIM, V1, P1427

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