THERMODYNAMICS OF THE WATER-FOODSTUFF EQUILIBRIUM

被引:56
作者
NUNES, RV
ROTSTEIN, E
机构
[1] PLAPIQUI (UNS-CONICET), 8000, Bahia Blanca
关键词
BET; ENTHALPY; ENTROPY; MONOLAYER; SORPTION;
D O I
10.1080/07373939108916643
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The thermodynamic analysis of the water-foodstuff equilibrium is reviewed, showing how partial molar and integral enthalpies and entropies can be obtained and indicating how to manipulate the experimental data for this purpose. The need for accurate and precise data is stressed and one experimental approach is recommended. Experimental results of desorption of water from Granny Smith apples provide information which is consistent from the thermodynamical standpoint. It is noted that the value of monolayer thickness corresponding to a minimum in integral entropy is substantially different from the value predicted by the BET equation.
引用
收藏
页码:113 / 137
页数:25
相关论文
共 23 条
[1]  
Bettelheim F.A., Comments on Professor La Mer's letter, J. Colloide Int. Sci, 23, (1967)
[2]  
Everett D.H., Thermodynamics of adsorption. Part I. General Considerations, Trans. Faraday Soc, 46, pp. 453-459, (1950)
[3]  
Flood E.A., The Gas Solid Interface, 2, (1967)
[4]  
Gal S., Recent developments in techniques for obtaining complete sorption isotherms, Water activity: influences on food quality, pp. 89-110, (1981)
[5]  
Gibbs J.W., The collected Works of J. Willard Gibbs, (1957)
[6]  
Hill T.L., Emmett P.H., Joyner L.G., Calculation of thermodynamic functions of adsorbed molecules from adsorption isotherm measurements: nitrogen on graphon, J. Am. Chem. Soc, 73, pp. 5102-5107, (1951)
[7]  
Hill T.L., Statistical mechanics of adsorption. V. Thermodynamics and heat of adsorption, J. Chem. Phys, 17, pp. 520-535, (1949)
[8]  
Hill T.L., Statistical mechanics of adsorption. IX. Adsorption thermodynamics and solution thermodynamics, J. Chem. Phys, 18, pp. 246-256, (1950)
[9]  
Hill T.L., Theory of physical adsorption, Advan. Catalysis, 4, pp. 212-258, (1952)
[10]  
Le Maguer M., Application of solution thermodynamics to water sorption in food system, (1983)