HYDROGEN-ATOM ABSTRACTION REACTION BY TRIPLET PYRAZINE AT LOW-TEMPERATURE

被引：11

作者：

JINGUJI, M ^{[1
]}

HOSAKO, Y ^{[1
]}

OBI, K ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT CHEM,MEGURO KU,TOKYO 152,JAPAN

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1979年 / 83卷 / 19期

关键词：

D O I：

10.1021/j100482a025

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The hydrogen atom abstraction reaction of the triplet pyrazine at low temperature was studied. Activation energies for pyrazyl stabilization and phosphorescence quenching agree with each other and are 2.1-2.3 kcal mol-1. This value shows the activation energy of the hydrogen abstraction reaction by the triplet pyrazine. The effect of the solvent cage is negligible in this case. © 1979 American Chemical Society.

引用

页码：2551 / 2553

页数：3

共 6 条

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