STEREOSELECTIVE HYDROLYSIS OF AMINO-ACID ESTERS BY DIPEPTIDE CATALYSTS AND BY N-DECANOYL-HISTIDINE IN SURFACTANT AGGREGATE DOMAINS

被引：1

作者：

IHARA, Y ^{[1
]}

NAKANISHI, E ^{[1
]}

AKIYAMA, A ^{[1
]}

YAMAMOTO, H ^{[1
]}

机构：

[1] UNIV OSAKA PREFECTURE,DEPT APPL CHEM,SAKAI,OSAKA 591,JAPAN

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1989年 / 27卷 / 01期

关键词：

Amino Acids--Performance - Catalysts--Biological Materials - Chemical Reactions--Catalysts - Enzymes--Performance - Surface Active Agents--Applications;

D O I：

10.1002/pola.1989.080270108

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The rate constants of hydrolysis of the enantiomers of amino acid nitrophenyl esters by catalytic domains composed of cationic surfactant aggregates and either dipeptide catalysts or Ni-decanoyl-L-histidine have been determined at pH 7.30. The dipeptide catalysts show large range enhancement and stereoselectivity in aggregate domains. The surfactant structural effects are examined by investigation of the rate constants and stereoselectivities, and the nature of stereoselective catalysis is discussed.

引用

页码：87 / 97

页数：11

共 36 条

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MATSUMOTO, Y
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BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1983, 56 (11) : 3370 - 3375
[22] STEREOSELECTIVE MICELLAR CATALYSIS - REACTIONS OF AMINO-ACID ESTER DERIVATIVES WITH N-ACYL-L-HISTIDINE IN MICELLES
IHARA, Y
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1980, (10): : 1483 - 1487
[23] STEREOSELECTIVE HYDROLYSIS OF AMINO-ACID PARA-NITROPHENYL ESTERS BY POLY(ETHYLENIMINE) DERIVATIVES WITH OPTICALLY-ACTIVE GROUPS
NANGO, M
KOZUKA, H
KIMURA, Y
KUROKI, N
IHARA, Y
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JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1980, 18 (10) : 647 - 651
[24] STEREOSELECTIVE DEACYLATION OF LONG-CHAIN AMINO-ACID ESTERS WITH MIXED MICELLES OF L-HISTIDINE DERIVATIVES AND CATIONIC SURFACTANTS
OHKUBO, K
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JOURNAL OF MOLECULAR CATALYSIS, 1981, 12 (01): : 125 - 128
[25] ENANTIOSELECTIVITY ENHANCEMENT IN THE DEACYLATION OF N-ACYL AMINO-ACID ESTERS BY VESICULAR SYSTEMS OF LONG-CHAIN DIPEPTIDE NUCLEOPHILES AND A CATIONIC DOUBLE CHAIN SURFACTANT
OHKUBO, K
MATSUMOTO, N
NAGASAKI, M
YAMAKI, K
OGATA, H
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1984, 57 (01) : 214 - 218
[26] METAL-ION AND MICELLAR TRIGGERING OF ENANTIOSELECTIVITY IN THE HYDROLYSIS OF N-PROTECTED AMINO-ACID ESTERS
WEIJNEN, JGJ
KOUDIJS, A
ENGBERSEN, JFJ
JOURNAL OF MOLECULAR CATALYSIS, 1992, 73 (01): : L5 - L9
[27] DIPEPTIDE ESTER COMPLEXES OF PLATINUM(II) FROM REACTION OF N-COORDINATED ALPHA-AMINO ACIDS WITH AMINO-ACID ESTERS
PURUCKER, B
BECK, W
ZEITSCHRIFT FUR NATURFORSCHUNG PART B-CHEMIE BIOCHEMIE BIOPHYSIK BIOLOGIE UND VERWANDTEN GEBIETE, 1972, B 27 (10): : 1140 - &
[28] HYDROLYSIS OF ACTIVE ESTERS OF ALIPHATIC CARBOXYLIC-ACIDS WITH CYCLIC DIPEPTIDE CATALYSTS CONSISTING OF L-HISTIDINE AND DIFFERENT ALIPHATIC ALPHA-AMINO-ACIDS
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BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (02) : 497 - 504
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URATA, Y
HIROTA, S
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SAGAWA, T
YOSHINAGA, K
KOBUNSHI RONBUNSHU, 1995, 52 (10) : 644 - 649
[30] ACTIVATION-PARAMETER RELATIONSHIPS IN ASYMMETRICALLY SELECTIVE HYDROLYSIS OF AMINO-ACID ESTERS CATALYZED BY L-HISTIDINE-COBALT(II) COMPLEXES
OHKUBO, K
ARIMA, H
YOSHINAGA, K
INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1978, 14 (8-9): : 287 - 292

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