STEREOSELECTIVE HYDROLYSIS OF AMINO-ACID ESTERS BY DIPEPTIDE CATALYSTS AND BY N-DECANOYL-HISTIDINE IN SURFACTANT AGGREGATE DOMAINS

被引：1

作者：

IHARA, Y ^{[1
]}

NAKANISHI, E ^{[1
]}

AKIYAMA, A ^{[1
]}

YAMAMOTO, H ^{[1
]}

机构：

[1] UNIV OSAKA PREFECTURE,DEPT APPL CHEM,SAKAI,OSAKA 591,JAPAN

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1989年 / 27卷 / 01期

关键词：

Amino Acids--Performance - Catalysts--Biological Materials - Chemical Reactions--Catalysts - Enzymes--Performance - Surface Active Agents--Applications;

D O I：

10.1002/pola.1989.080270108

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The rate constants of hydrolysis of the enantiomers of amino acid nitrophenyl esters by catalytic domains composed of cationic surfactant aggregates and either dipeptide catalysts or Ni-decanoyl-L-histidine have been determined at pH 7.30. The dipeptide catalysts show large range enhancement and stereoselectivity in aggregate domains. The surfactant structural effects are examined by investigation of the rate constants and stereoselectivities, and the nature of stereoselective catalysis is discussed.

引用

页码：87 / 97

页数：11

共 36 条

[1] CATALYSIS OF ENANTIOMERIC ESTER HYDROLYSIS IN POLYMER DOMAINS - CATALYTIC EFFECTS OF N-DECANOYL-HISTIDINE AND OF DIPEPTIDE DERIVATIVES CONTAINING A HISTIDYL RESIDUE
KIMURA, Y
TANAKA, A
NANGO, M
KUROKI, N
IHARA, Y
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1984, 22 (02) : 407 - 417
[2] STEREOSELECTIVE HYDROLYSIS OF AMINO-ACID ESTERS IN MODIFIED LINEAR POLY(ETHYLENIMINE) DOMAINS
KIMURA, Y
KANDA, S
NANGO, M
IHARA, Y
KOGA, J
KUROKI, N
CHEMISTRY LETTERS, 1984, (03) : 433 - 436
[3] STEREOSELECTIVE HYDROLYSIS OF AMINO-ACID ESTERS CATALYZED BY BETA-CYCLODEXTRIN-L(OR D)-HISTIDINE COMPOUNDS
OHKUBO, K
NAGAMURA, H
ISRAEL JOURNAL OF CHEMISTRY, 1985, 25 (3-4) : 241 - 245
[4] ENANTIOSELECTIVE HYDROLYSIS OF DIPEPTIDE AMINO-ACID ESTERS BY DIPEPTIDE-TYPE AND TRIPEPTIDE-TYPE L-HISTIDINE DERIVATIVES IN A BILAYER VESICULAR SYSTEM
OHKUBO, K
OGATA, H
YAMAKI, K
YAMASHITA, K
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1984, 185 (05): : 891 - 897
[5] TRIFLUOROACETYLATION OF AMINO-ACID ESTERS AND DIPEPTIDE ESTERS WITH N-TRIFLUOROACETYL-POLYAMIDE 66
TESCH, HW
SCHULZ, RC
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1981, 182 (11): : 2981 - 2988
[6] STEREOSELECTIVE HYDROLYSIS OF AMINO-ACID ESTERS BY MODIFIED POLY(ETHYLENIMINE)S WITH COVALENTLY-LINKED DIPEPTIDE CONTAINING A HISTIDYL RESIDUE
KIMURA, Y
NANGO, M
IHARA, Y
KUROKI, N
CHEMISTRY LETTERS, 1984, (03) : 429 - 432
[7] STEREOSELECTIVE HYDROLYSIS OF AMINO-ACID ESTERS IN BRANCHED OR LINEAR POLY(ETHYLENIMINE) DERIVATIVES
NANGO, M
KIMURA, Y
IHARA, Y
KUROKI, N
MACROMOLECULES, 1988, 21 (08) : 2330 - 2335
[8] EFFICIENT STEREOSELECTIVE HYDROLYSIS OF ENANTIOMERIC AMINO-ACID ESTERS BY BILAYER VESICULAR SYSTEMS WHICH INCLUDE DI-PEPTIDE OR TRI-PEPTIDE HISTIDINE CATALYSTS
OHKUBO, K
MIYAKE, S
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (08): : 995 - 1001
[9] STEREOSELECTIVE DIFFERENTIATION IN HETEROGENEOUS METHANOLYSIS OF AMINO-ACID NITROPHENYL ESTERS BY POWDERED POLY(N-METHACRYLOYL-L-HISTIDINE)
OKUDA, Y
YOSHIHARA, M
MAESHIMA, T
MAKROMOLEKULARE CHEMIE-RAPID COMMUNICATIONS, 1987, 8 (11): : 579 - 582
[10] EFFICIENT MULTIPOINT INTERACTION BETWEEN PEPTIDE CATALYSTS AND AMINO-ACID ESTERS IN A BILAYER VESICULAR MEMBRANE FOR HIGHLY STEREOSELECTIVE HYDROLYSIS REACTIONS
OHKUBO, K
URABE, K
YAMAMOTO, J
ISHIDA, H
USUI, S
SAGAWA, T
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (22) : 2301 - 2302

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