STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .28. SOLVOLYSIS OF 1-ARYL-1-CYCLOPROPYL 3,5-DINITROBENZOATES CONTAINING STRONGLY ELECTRON-SUPPLYING ARYL GROUPS - EVIDENCE FOR 2 DISTINCT REACTION PROCESSES INVOLVING ASSISTED (K-DELTA) AND UNASSISTED (KC) MECHANISMS

被引：26

作者：

BROWN, HC

RAO, CG

RAVINDRANATHAN, M

机构：

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1978年 / 100卷 / 25期

关键词：

D O I：

10.1021/ja00493a026

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：7946 / 7953

页数：8

共 55 条

[11] RELATIVE RATES OF BROMINATION OF BENZENE AND THE METHYLBENZENES - PARTIAL RATE FACTORS FOR THE BROMINATION REACTION [J].

BROWN, HC ;

STOCK, LM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (06) :1421-1425

[12] SOLVOLYSIS OF 3-ARYL-3-NORTRICYCLYL P-NITROBENZOATES - EVIDENCE FOR MAJOR INCREASES IN ELECTRON SUPPLY BY CYCLOPROPYL GROUP WITH INCREASING ELECTRON DEMAND AT CATIONIC CENTER [J].

BROWN, HC ;

PETERS, EN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (07) :1927-1929

[13] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .23. NEW SIGMA-+ CONSTANTS FOR ACTIVATING SUBSTITUENTS - SOLVOLYSIS OF 1-ARYL-1-CYCLOPROPYL 3,5-DINITROBENZOATES CONTAINING ACTIVATING SUBSTITUENTS IN ARYL GROUP - TOOL OF INCREASING ELECTRON DEMAND AND I-STRAIN [J].

BROWN, HC ;

RAO, CG ;

RAVINDRANATHAN, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (23) :7663-7667

[14] CHEMICAL EFFECTS OF STERIC STRAINS .6. THE EFFECT OF RING SIZE ON THE RATE OF SOLVOLYSIS OF THE 1-CHLORO-1-METHYLCYCLOALKANES [J].

BROWN, HC ;

BORKOWSKI, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1952, 74 (08) :1894-1902

[15] SOLVOLYSIS OF 2-ARYL-2-BICYCLO[2.1.1]HEXYL PARA-NITROBENZOATES - EVIDENCE FOR ABSENCE OF SIGMA-PARTICIPATION BY APPLICATION OF TOOL OF INCREASING ELECTRON DEMAND [J].

BROWN, HC ;

RAVINDRANATHAN, M ;

RAO, CG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (07) :2359-2361

[16] I-STRAIN AS A FACTOR IN THE CHEMISTRY OF RING COMPOUNDS [J].

BROWN, HC ;

FLETCHER, RS ;

JOHANNESEN, RB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) :212-221

[17] HIGH EXO - ENDO RATE RATIO AND PREDOMINANT EXO SUBSTITUTION IN SOLVOLYSIS OF 2-P-ANISYLNORBORNYL DERIVATIVES . CHARACTERISTICS OF A HIGHLY STABILIZED CLASSICAL NORBORNYL CATION [J].

BROWN, HC ;

TAKEUCHI, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (10) :2691-&

[18] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .11. RATES AND PRODUCTS OF SOLVOLYSIS OF 2-ARYL-2-NORBORNENYL-PARA-NITROBENZOATES AND 2-METHYL-2-NORBORNENYL PARA-NITROBENZOATES - EXO-ENDO RATE RATIO AS A FUNCTION OF INCREASING ELECTRON DEMAND [J].

BROWN, HC ;

PETERS, EN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (26) :7442-7448

[19] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .21. SOLVOLYSIS OF 2-ARYL-2-NORBORNYL AND 2-ARYL-2-CAMPHENILYL PARA-NITROBENZOATES - CRITICAL-EXAMINATION OF IMPORTANCE OF SIGMA-PARTICIPATION IN SOLVOLYSIS TERTIARY 2-NORBORNYL DERIVATIVES BY APPLICATION OF TOOL OF INCREASING ELECTRON DEMAND [J].

BROWN, HC ;

TAKEUCHI, K ;

RAVINDRANATHAN, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (08) :2684-2690

[20] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .12. SOLVOLYSIS OF 2-ARYL-5-METHYL-2-NORBORNENYL-PARA-NITRO-BENZOATES AND 2,5-DIMETHYL-2-NORBORNENYL PARA-NITROBENZOATES - EVIDENCE FOR MAJOR PI PARTICIPATION REVEALED BY TOOL OF INCREASING ELECTRON DEMAND [J].

BROWN, HC ;

PETERS, EN ;

RAVINDRANATHAN, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (26) :7449-7453

← 1 2 3 4 5 6 →