(N,N,N',N'-Tetramethylethylenediamine-kappa N) bis(2,4,6-trimethylphenolato-kappa O)-germanium(II)

被引：1
|
作者：
Brusylovets, Oleksii [1 ]
Yrushnikov, Oleg [1 ]
Naumova, Dina [1 ]
Klishin, Nikolai [1 ]
Rusanov, Eduard [2 ]
机构：
[1] Kiev Natl Taras Shevchenko Univ, Dept Chem, Volodymyrska St 64, UA-01601 Kiev, Ukraine
[2] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02660 Kiev, Ukraine
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
data-to-parameter ratio = 19.6; mean σ(C-C) = 0.003 Å; R factor = 0.030; single-crystal X-ray study; T = 173 K; wR factor = 0.082;
D O I：
10.1107/S160053681200503X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Ge(C 9H 11O) 2(C 6H 16N 2)], the Ge II atom is coordinated in a distorted trigonalpyramidal geometry by two O atoms belonging to two 2,4,6-trimethylphenolate ligands and one N atom of a tetramethylethylenediamine ligand. Comparing the structure with published data of similar compounds shows that the Ge - O bonds are covalent and the Ge - N bond is coordinated.
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收藏
页码：M296 / U716
页数：9
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