4-Acetyl-2-hydroxy-2,5-dimethylfuran-3(2H)-one

被引：5

作者：

Akazaki, Chiaki ^{[1
]}

Kawabata, Shun ^{[1
]}

Nishino, Hiroshi ^{[2
]}

机构：

[1] Kumamoto Univ, Grad Sch Sci & Technol, Dept Chem, Kurokami 2-39-1, Kumamoto 8608555, Japan

[2] Kumamoto Univ, Dept Chem, Kurokami 2-39-1, Kumamoto 8608555, Japan

来源：

MOLBANK | 2016年 / 04期

基金：

日本学术振兴会;

关键词：

4-acetyl-2-hydroxy-2,5-dimethylfuran-3(2H)-one; keto-hemiacetal; Mn(acac)(3); Mn(OAc)(3); aerobic oxidation; 2,4-pentanedione; cyclic acetal; trifluoroethanol;

D O I：

10.3390/M913

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The facile synthesis of 4-acetyl-2-hydroxy-2,5-dimethylfuran-3(2H)-one (4) was achieved by the Mn(OAc) 3-mediated aerobic oxidation of 2,4-pentanedione or the direct reaction of Mn(acac)(3) in AcOH-TFE at room temperature under a dried air stream.

引用

页数：7

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