INSITU GENERATION OF PH3P=C(CF3)2 - FACILE ONE POT CONVERSION OF ALDEHYDES TO BIS-TRIFLUOROMETHYL OLEFINS

被引：11

作者：

BURTON, DJ

INOUYE, Y

机构：

[1] Department of Chemistry, University of Iowa, Iowa City

来源：

TETRAHEDRON LETTERS | 1979年 / 20卷 / 36期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(01)95419-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The in situ reaction of triphenylphosphine with tetrakis(trifluoromethyl)-1,3-dithietane in the presence of aliphatic or aromatic aldehydes gives good to excellent yields of bis-trifluoromethyl olefins. © 1979.

引用

页码：3397 / 3400

页数：4

共 16 条

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[2]

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[3] TRIALKYLAMMONIUM-2,2,3,3,4,4-HEXAFLUOROCYCLOBUTANE YLIDES - PREPARATION AND ISOLATION OF AN UNUSUALLY STABLE FLUORINATED CARBANION [J].

BURTON, DJ ;

HOWELLS, RD ;

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BURTON, DJ ;

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BURTON, DJ ;

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[6]

BURTON DJ, J AM CHEM SOC

[7] FLUORO OLEFINS .I. SYNTHESIS OF BETA-SUBSTITUTED PERFLUORO OLEFINS [J].

HERKES, FE ;

BURTON, DJ .

JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (05) :1311-&

[8] CRYSTAL-STRUCTURE OF 2,2,3,3,4,4-HEXAFLUORO-(TRIPHENYLPHOSPHORANYLIDENE)CYCLOBUTANE [J].

HOWELLS, MA ;

HOWELLS, RD ;

BAENZIGE.NC ;

BURTON, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (16) :5366-5370

[9]

HOWELLS RD, UNPUBLISHED

[10]

KYATKIN BL, 1973, TETRAHEDRON, V29, P2759

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