CHROMATOGRAPHIC INVESTIGATIONS OF MACROMOLECULES IN THE CRITICAL RANGE OF LIQUID-CHROMATOGRAPHY .6. ANALYSIS OF THE METHYL-METHACRYLATE BLOCK IN BLOCK-COPOLYMERS OF DECYL AND METHYL-METHACRYLATE

被引：35

作者：

PASCH, H

AUGENSTEIN, M

TRATHNIGG, B

机构：

[1] ROHM GMBH CHEM FABRIK,KIRSCHENALLEE,D-64293 DARMSTADT,GERMANY

[2] KARL FRANZENS UNIV,INST ORGAN CHEM,DEPT POLYMER CHEM,HEINRICHSTR 28,A-8010 GRAZ,AUSTRIA

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 1994年 / 195卷 / 02期

关键词：

D O I：

10.1002/macp.1994.021950231

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Using liquid chromatography at the critical point of adsorption the molar mass and the polydispersity of the individual blocks in block copolymers of decyl and methyl methacrylate are determined. In addition, the total molar mass and the chemical composition of the block copolymers are calculated and compared to data from conventional size exclusion chromatography (SEC) and SEC with coupled density-refractive index detection. The agreeement of the data obtained by the different methods is found to be very good.

引用

页码：743 / 750

页数：8

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