EFFICIENCY OF TRIBUTYLTIN EXTRACTION FROM RHINE RIVER SEDIMENT

被引：22

作者：

CAI, Y ^{[1
]}

RAPSOMANIKIS, S ^{[1
]}

ANDREAE, MO ^{[1
]}

机构：

[1] MAX PLANCK INST CHEM,DEPT BIOGEOCHEM,POB 3060,W-6500 MAINZ,GERMANY

来源：

MIKROCHIMICA ACTA | 1992年 / 109卷 / 1-4期

关键词：

TBT; GC-AAS; SEDIMENT; EXTRACTION EFFICIENCY;

D O I：

10.1007/BF01243212

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A Rhine river sediment sample was spiked with tributyltin (TBT), equilibrated for ten days and the tributyltin extraction efficiency was optimised using a simplex algorithm. Analysis was effected using hydride generation gas chromatography-atomic absorption spectroscopy (GC-AAS) apparatus. The results show that, in this sediment sample, different molarities of HCl in methanol extract different species with varying extraction efficiencies. The least polar extraction solution extracted TBT more efficiently, whilst DBT and MBT require molar solution of HCl in methanol for efficient extraction.

引用

页码：67 / 71

页数：5