SEPARATION OF BROMIDE, BROMATE, IODIDE, IODATE, NITRITE, NITRATE AND SELENITE ANIONS BY CAPILLARY ZONE ELECTROPHORESIS

被引:42
作者
AMRAN, MB
LAKKIS, MD
LAGARDE, F
LEROY, MJF
LOPEZSANCHEZ, JF
RAURET, G
机构
[1] EHICS,CNRS,URA 405,CHIM MINERALE & ANALYT LAB,1 RUE BLAISE PASCAL,F-67008 STRASBOURG,FRANCE
[2] UNIV BARCELONA,DEPT QUIM ANALIT,E-08028 BARCELONA,SPAIN
来源
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 1993年 / 345卷 / 06期
关键词
D O I
10.1007/BF00325618
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Capillary zone electrophoresis (CZE) has been used for the separation of bromide, bromate, iodide, iodate, nitrite, nitrate and selenite anions. The separation was achieved using a fused silica capillary (72 cm long x 50 mum i.d.) filled with an acidic phosphate buffer (pH = 3, 25 mmol/1), and with on-column UV detection at 200 nm. The influence of different experimental parameters such as pH, ionic strength and voltage, was studied. The nitrate concentration of a Rhine water sample was then determined under selected conditions and the results were compared to those obtained by high performance ion chromatography (HPIC).
引用
收藏
页码:420 / 423
页数:4
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