CHEMOSELECTIVE ALKYLATION OF THIOLS - A DETAILED INVESTIGATION OF REACTIONS OF THIOLS WITH HALIDES

被引：46
|
作者：
KHURANA, JM
SAHOO, PK
机构：
[1] Department of Chemistry, University of Delhi
来源：
SYNTHETIC COMMUNICATIONS | 1992年 / 22卷 / 12期
关键词：
D O I：
10.1080/00397919208020489
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Arylthiols, aralkylthiols and alkane thiols can be readily alkylated by alkyl/aralkyl halides in presence of K2CO3/DMF to yield unsymmetrical sulphides in nearly quantitative yields. 2-Mercaptoethanol gave the thioether chemoselectively.
引用
收藏
页码：1691 / 1702
页数：12
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