ASYMMETRIC LIGANDS FOR TRANSITION-METAL-CATALYZED REACTIONS - 2-DIPHENYLPHOSPHINOBENZOYL DERIVATIVES OF C2-SYMMETRICAL DIOLS AND DIAMINES

被引：179

作者：

TROST, BM

VANVRANKEN, DL

机构：

[1] Department of Chemistry, Stanford University, Stanford, California

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 02期

关键词：

D O I：

10.1002/anie.199202281

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

For Pd-catalyzed allylic alkylations a series of novel C2-symmetric bis-(diphenylphosphino) ligands have proved to be extremely efficient. For example, the model reaction 1 --> 2 with diamide 3 as ligand proceeds in 94% yield and 88% ee. Ts = para-toluolsulfonyl, dba = dibenzylidenacetoacetonate.

引用

页码：228 / 230

页数：3

共 43 条

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