SOLVOLYTIC STEREOSELECTIVE COUPLING REACTION OF P-METHOXYPHENYLMAGNESIUM BROMIDE WITH SUBSTITUTED ALLYLIC CHLORIDES

被引：9

作者：

LAJIS, NH

KHAN, MN

机构：

来源：

TETRAHEDRON | 1992年 / 48卷 / 06期

关键词：

D O I：

10.1016/S0040-4020(01)88206-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The alpha- and gamma-coupling reactions of a few substituted allylic chlorides with p-methoxyphenylmagnesium bromide were concluded as to invovle the formation of an intimate ion-pair intermediate. The solvents used gave substantial effects both on the regio-and stereo-selectivity of the reaction.

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页码：1109 / 1114

页数：6

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