COBALT(II)-PORPHYRIN CATALYZED SELECTIVE FUNCTIONALIZATION OF ALKANES WITH SULFURYLCHLORIDE - A REMARKABLE SUBSTITUENT EFFECT

被引：7

作者：

KHANNA, V ^{[1
]}

TAMILSELVAN, P ^{[1
]}

KALRA, SJS ^{[1
]}

IQBAL, J ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,DEPT CHEM,KANPUR 208016,UTTAR PRADESH,INDIA

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 32期

关键词：

D O I：

10.1016/S0040-4039(00)78223-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cobalt(II)-porphyrin complex 1 and 2 catalyses the chlorination and sulfochlorination respectively of n-alkanes and cycloalkanes with sulfuryl chloride in benzene. The p-substituent of the benzene ring in the prophyrin complex 1 and 2 shows a remarkable chemoselectivity in these reactions.

引用

页码：5935 / 5938

页数：4

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