INTERACTION OF EGG LECITHIN WITH PI-ELECTRON ACCEPTORS

被引：0
|
作者：
CHATTERJEE, I [1 ]
SENVARMA, C [1 ]
BHOWMIK, BB [1 ]
机构：
[1] JADAVPUR UNIV,DEPT CHEM,CALCUTTA 700032,W BENGAL,INDIA
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1993年 / 32卷 / 07期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Spectral studies show that egg lecithin forms 1:1 molecular complexes with different pi-electron acceptors such as picric acid, tetracyanoethylene and chloranil in chloroform. In water the pi-electron acceptors are already complexed and the spectra of these pi-electron acceptors are not further perturbed in the presence of egg lecithin. Thermodynamic and spectrophotometric properties of the complexes show that the acceptor strengths of the pi-electron acceptors studied are in the order, picric acid>tetracyanoethylene>chloranil. The exact site of interaction of electron acceptor in egg lecithin has also been identified.
引用
收藏
页码：561 / 564
页数：4
相关论文
共 50 条
  • [1] REACTION OF POLYPHENYLACETYLENE WITH PI-ELECTRON ACCEPTORS
    ORLOV, IG
    KUTAFINA, NS
    GOLUBENKO, LI
    CHERKASHIN, MI
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1981, 30 (02): : 219 - 223
  • [2] CHARGE-TRANSFER INTERACTION OF CROWN THIOETHERS WITH PI-ELECTRON ACCEPTORS
    HAMED, MMA
    ELNADY, AM
    BAKR, M
    MAHMOUD, MR
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1993, 83 (1-4): : 183 - 189
  • [3] CHARGE-TRANSFER INTERACTION OF CAFFEINE WITH PI-ELECTRON AND SIGMA-ELECTRON ACCEPTORS
    HAMED, HMA
    SPECTROSCOPY LETTERS, 1994, 27 (02) : 197 - 208
  • [4] CATIONIC POLYMERIZATION IN PRESENCE OF PI-ELECTRON ACCEPTORS
    PANAYOTOV, IM
    HEUBLEIN, G
    JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1977, A11 (11): : 2065 - 2086
  • [5] CATIONIC POLYMERIZATION OF STYRENE IN PRESENCE OF PI-ELECTRON ACCEPTORS
    PANAYOTO.IM
    DIMITROV, IK
    BAKERDJI.IE
    JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1969, 7 (8PA1): : 2421 - &
  • [6] MOLECULAR-COMPLEXES OF IMIDAZOLES WITH PI-ELECTRON ACCEPTORS
    ABDALLA, EM
    CANADIAN JOURNAL OF APPLIED SPECTROSCOPY, 1993, 38 (03): : 88 - 93
  • [7] INTERACTION OF PERPENDICULAR PI-ELECTRON SYSTEMS
    JAFFE, HH
    CHALVET, O
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (11) : 1561 - &
  • [8] MOLECULAR-COMPLEXES OF MACROCYCLIC POLYAMINES WITH PI-ELECTRON ACCEPTORS
    HAMED, MMA
    BAKR, M
    MAHMOUD, MR
    SPECTROSCOPY LETTERS, 1995, 28 (01) : 29 - 42
  • [9] MOLECULAR-COMPLEXES OF BENZYLIDENEANILINES WITH SOME PI-ELECTRON ACCEPTORS
    HAMED, MMA
    ELGYAR, SA
    ELNADY, A
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1987, 26 (09): : 728 - 731
  • [10] Interaction of N-tert-butylaziridine with pi-electron acceptors .2. Polymerization initiated by tetracyanoethylene
    Christova, DC
    Velichkova, RS
    Panayotov, IM
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 1996, 197 (09) : 2639 - 2646
12345