CRYSTAL-GROWTH OF BORON MONOPHOSPHIDE FROM METAL PHOSPHIDE SOLUTIONS

被引：23

作者：

CHU, TL ^{[1
]}

JACKSON, JM ^{[1
]}

SMELTZER, RK ^{[1
]}

机构：

[1] SO METHODIST UNIV,ELECTR SCI CTR,DALLAS,TX 75222

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1973年 / 120卷 / 06期

关键词：

SEMICONDUCTING BORON - SEMICONDUCTOR MATERIALS - Growth;

D O I：

10.1149/1.2403566

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The crystal growth of boron phosphide, BP, has been investigated using two approaches: (i) the addition of phosphorus to a boron-nickel or boron-copper melt, and (ii) the recrystallization of boron phosphide from a nickel phosphide or copper phosphide solution in a temperature gradient. To determine the optimum conditions for the growth processes, the solubility of boron phosphide in nickel phosphide (Ni//1//2P//5) and copper subphosphide (Cu//3P) was determined over a wide temperature range. The solubility of boron phosphide in nickel phosphide was found to be higher than that in copper phosphide. The temperature gradient recrystallization of boron phosphide from nickel phosphide at 1200 C has produced larger crystals. The solution-grown crystals were in the form of hoppers and platelets with platelets dominating. Because of its large energy gap, boron monophosphide has potential applications for high temperature devices and for visible light-emitting devices.

引用

页码：802 / 806

页数：5

共 13 条

[1]

BARANOV BV, 1967, IZV AKAD NAUK SSSR N, V3, P1691

[2] CRYSTALS AND EPITAXIAL LAYERS OF BORON PHOSPHIDE [J].

CHU, TL ;

JACKSON, JM ;

HYSLOP, AE ;

CHU, SC .

JOURNAL OF APPLIED PHYSICS, 1971, 42 (01) :420-&

[3] GROWTH OF SEMICONDUCTOR CRYSTALS FROM SOLUTION USING TWIN-PLANE REENTRANT-EDGE MECHANISM [J].

FAUST, JW ;

JOHN, HF .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1964, 25 (12) :1407-&

[4]

Hansen M., 1958, J ELECTROCHEM SOC, DOI DOI 10.1149/1.2428700

[5] Contributions to systematic relations science - Copper phosphite [J].

Haraldsen, H .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1939, 240 (04) :337-354

[6] PREPARATION OF BP SINGLE-CRYSTALS FROM B-NI-P SOLUTION [J].

IWAMI, M ;

KAWABE, K ;

FUJITA, N .

JAPANESE JOURNAL OF APPLIED PHYSICS, 1971, 10 (12) :1746-&

[7]

LARSSON E, 1965, ARK KEMI, V23, P335

[8] CRYSTAL STRUCTURES OF CUP2 AND AGP2 WITH SOME PHASE ANALYTICAL DATA OF CU-P AND AG-P SYSTEMS [J].

OLOFSSON, O .

ACTA CHEMICA SCANDINAVICA, 1965, 19 (01) :229-&

[9] THE CRYSTAL STRUCTURE OF NI12P5 [J].

RUNDQVIST, S ;

LARSSON, E .

ACTA CHEMICA SCANDINAVICA, 1959, 13 (03) :551-560

[10]

SHUNK FA, 1969, CONSTITUTION BINARY

← 1 2 →