SYNTHESIS OF 2,3-DI-O-PHYTANYL-1-O-(ALPHA-D-GLUCOPYRANOSYL)-SN-GLYCEROL DERIVATIVES, ANALOGS OF POLAR LIPIDS ISOLATED FROM A HALOPHILIC BACTERIAL STRAIN

被引：3

作者：

KAMIKAWA, T

NOGAWA, K

YAMAGIWA, Y

机构：

[1] Department of Chemistry, Faculty of Science and Technology, Higashi-Osaka, 577, Kowakae

来源：

GLYCOCONJUGATE JOURNAL | 1993年 / 10卷 / 03期

关键词：

SULFOGLYCOLIPID; PHOSPHONOGLYCOLIPID; GLYCEROL ETHER LIPIDS; SYNTHESIS;

D O I：

10.1007/BF00702205

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

2,3-Di-O-phytanyl-1-O-glucopyranosylglycerol and polar derivatives of its 6'-glucose moiety have been synthesized. The target molecule contains the diphytanyl-sn-glycerol moiety which is alpha-linked to glucose. The key step in its synthesis involves the coupling of phytanyl bromide and isopropylidene threitol. We also demonstrated that the 6'-hydroxyl group of glycolipids can be functionalized without protection of the sugar moiety.

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页码：235 / 239

页数：5

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