CYCLOPENTADIENYL ACTINIDE COMPLEXES - BONDING AND ELECTRONIC-STRUCTURE

被引：91
作者：
BURSTEN, BE
STRITTMATTER, RJ
机构：
[1] Department of Chemistry, Ohio State University, Columbus, Ohio
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1991年 / 30卷 / 09期
关键词：
D O I：
10.1002/anie.199110691
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Organoactinoid complexes are very rare, and because of difficulties in their handling are often limited to the metals Th and U. Nevertheless similarities and differences between the numerous d‐element and f‐element complexes emerge, in this review particularly with regard to the bonding situations, which have been studied with the help of modern computational methods. An especially aesthetic organoactinoid complex, which has no analogues in the transition‐metals, is [Cp4An] 1 (An = actinoid). (Figure Presented.)
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页码：1069 / 1085
页数：17
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