ENZYME-CATALYZED SYNTHESIS OF (S)-CYANOHYDRINS

被引：69

作者：

NIEDERMEYER, U ^{[1
]}

KULA, MR ^{[1
]}

机构：

[1] FORSCHUNGSZENTRUM JULICH, UNIV DUSSELDORF, INST ENZYMTECHNOL, POSTFACH 2050, W-5170 JULICH 1, GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1990年 / 29卷 / 04期

关键词：

D O I：

10.1002/anie.199003861

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An oxynitrilase from Sorghum bicolor is a highly stereoselective catalyst for the addition of hydrogen cyanide to homocyclic aromatic aldehydes, leading to (S)‐cyanohydrins. Reaction in aqueous medium results in ee‐values as high as 99%. Reactions with this catalyst can be carried out in a continuous fashion. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：386 / 387

页数：2

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