MECHANISM OF ELECTROREDUCTION OF NICKEL(II) COMPLEXES WITH MALONIC AND SUCCINIC ACID AT A DROPPING MERCURY-ELECTRODE

被引：6

作者：

URBANSKA, J

机构：

[1] Institute of Chemistry, University of Wroclaw, 50-383 Wroclaw

来源：

ANALYTICA CHIMICA ACTA | 1992年 / 259卷 / 02期

关键词：

DC POLAROGRAPHY; NICKEL COMPLEXES; REDUCTION MECHANISM;

D O I：

10.1016/0003-2670(92)85381-F

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The mechanism of the electroreduction process for Ni(II) complexes with malonic and succinic acid at a dropping mercury electrode was established. Transfer coefficients, the electrode reaction rate constants and the stability constants of the Ni(II) complexes were determined. A comparison with the corresponding Co(II) complexes was made.

引用

页码：311 / 317

页数：7