MECHANISM OF ELECTROREDUCTION OF NICKEL(II) COMPLEXES WITH MALONIC AND SUCCINIC ACID AT A DROPPING MERCURY-ELECTRODE

被引：6
作者：
URBANSKA, J
机构：
[1] Institute of Chemistry, University of Wroclaw, 50-383 Wroclaw
来源：
ANALYTICA CHIMICA ACTA | 1992年 / 259卷 / 02期
关键词：
DC POLAROGRAPHY; NICKEL COMPLEXES; REDUCTION MECHANISM;
D O I：
10.1016/0003-2670(92)85381-F
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The mechanism of the electroreduction process for Ni(II) complexes with malonic and succinic acid at a dropping mercury electrode was established. Transfer coefficients, the electrode reaction rate constants and the stability constants of the Ni(II) complexes were determined. A comparison with the corresponding Co(II) complexes was made.
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页码：311 / 317
页数：7
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