(2E)-3-(Dimethylamino)-1-(4-fluoro-phenyl)prop-2-en-1-one

被引：1

作者：

Kant, Rajni ^{[1
]}

Gupta, Vivek K. ^{[1
]}

Kapoor, Kamini ^{[1
]}

Deshmukh, Madhukar B. ^{[2
]}

Patil, D. R. ^{[2
]}

Anbhule, P. V. ^{[2
]}

机构：

[1] Univ Jammu, Post Grad Dept Phys & Elect, X Ray Crystallog Lab, Jammu 180006, India

[2] Shivaji Univ, Dept Chem, Kolhapur 416004, Maharashtra, India

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

data-to-parameter ratio = 15.1; mean ̄(C-C) = 0.003 Å; R factor = 0.046; single-crystal X-ray study; T = 293 K; wR factor = 0.133;

D O I：

10.1107/S160053681204202X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C11H12FNO, the dihedral angle between the prop-2-en-1-one group and the benzene ring is 19.33 (6)degrees. The configuration of the keto group with respect to the olefinic double bond is s-cis. In the crystal, the molecules form dimers through aromatic pi-pi stacking interactions [centroid-centroid distance = 3.667 (1) angstrom] and are linked via C-H center dot center dot center dot O interactions into chains along the b axis.

引用

页码：O3110 / +

页数：7

共 9 条

[1]

[Anonymous], 2010, CRYSALIS PRO

[2] 3-Dimethylamino-1-(4-methylphenyl)prop-2-en-1-one [J].

Deng, Juean ;

Shen, Dongsheng ;

Zhou, Zongzhou .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 :O2-U1086

[3] Synthesis and anticonvulsant activity of enaminones Part 7. Synthesis and anticonvulsant evaluation of ethyl 4-[(substituted phenyl)amino]-6-methyl-2-oxocyclohex-3-ene-1-carboxylates and their corresponding 5-methylcyclohex-2-enone derivatives [J].

Eddington, ND ;

Cox, DS ;

Khurana, M ;

Salama, NN ;

Stables, JP ;

Harrison, SJ ;

Negussie, A ;

Taylor, RS ;

Tran, UQ ;

Moore, JA ;

Barrow, JC ;

Scott, KR .

EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2003, 38 (01) :49-64

[4]

Farrugia L.J., 1997, J APPL CRYSTALLOGR, V30, P565, DOI [DOI 10.1107/S0021889897003117, 10.1107/S0021889897003117]

[5] A highly efficient regioselective one-pot synthesis of 2,3,6-trisubstituted pyridines and 2,7,7-trisubstituted tetrahydroquinolin-5-ones using K5CoW12O40•3H2O as a heterogeneous recyclable catalyst [J].

Kantevari, Srinivas ;

Chary, Mahankhali Venu ;

Vuppalapati, Srinivasu V. N. .

TETRAHEDRON, 2007, 63 (52) :13024-13031

[6] Efficient synthesis of β-enaminoesters via highly stereoselective Reformatsky reaction with disubstituted formamides as novel electrophiles [J].

Ke, Yi-Yin ;

Li, Yu-Jin ;

Jia, Jian-Hong ;

Sheng, Wei-Jian ;

Han, Liang ;

Gao, Jian-Rong .

TETRAHEDRON LETTERS, 2009, 50 (13) :1389-1391

[7]

Omran F. A., 1997, ORG PREP PROCED INT, V65, P285

[8] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[9] Structure validation in chemical crystallography [J].

Spek, Anthony L. .

ACTA CRYSTALLOGRAPHICA SECTION D-STRUCTURAL BIOLOGY, 2009, 65 :148-155

← 1 →