CHAIN REACTION MECHANISM OF CELLULOSE PYROLYSIS

被引：27
作者：
CHATTERJEE, PK
机构：
[1] Personal Products Company, Division of Johnson & Johnson, Milltown, New Jersey
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 1968年 / 12卷 / 08期
关键词：
D O I：
10.1002/app.1968.070120807
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Chatterjee and Conrad1 studied the kinetics of pyrolysis of cotton cellulose in the temperature range 270–310°C and proposed a chain reaction mechanism. Lipska and Parker8 studied the pyrolysis of the α‐cellulose in the temperature range 250–300°C and interpreted the kinetic data differently. Both articles were published almost simultaneously. In this paper Lipska and Parker's complete data have been again analyzed and reinterpreted in light of the chain reaction mechanism. The energies of activation for initiation and propagation steps of the cellulose decomposition reaction are discussed. Copyright © 1968 John Wiley & Sons, Inc.
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页码：1859 / +
页数：1
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