THE SOLID-STATE SELF-ORGANIZATION OF A SELF-ASSEMBLED [2]CATENANE

被引：26

作者：

AMABILINO, DB ^{[1
]}

ASHTON, PR ^{[1
]}

STODDART, JF ^{[1
]}

MENZER, S ^{[1
]}

WILLIAMS, DJ ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI & TECHNOL,DEPT CHEM,CHEM CRYSTALLOG LAB,LONDON SW7 2AY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 21期

关键词：

D O I：

10.1039/c39940002475

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reluctance of a [2]catenane, comprised of macrocycles incorporating pi-donors and pi-accepters, to be catenated further to form a [3]catenane may be explained by the molecular arrangement revealed in the solid-state structure of the [a]catenane, which shows all aromatic units to be involved in intramolecular pi-pi stacking interactions; moreover, the molecules self-organise in the solid-state to form a quilt-like two-dimensional array by virtue of intermolecular pi-pi stacking interactions.

引用

页码：2475 / 2478

页数：4

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