COMPLEXES OF TRIS((2-PYRIDYL)ALKYL)AMINES WITH LITHIUM AND SODIUM-SALTS

被引：20

作者：

BROWNSTEIN, SK ^{[1
]}

PLOUFFE, PY ^{[1
]}

BENSIMON, C ^{[1
]}

TSE, J ^{[1
]}

机构：

[1] NATL RES COUNCIL CANADA,STEACIE INST MOLEC SCI,OTTAWA K1A 0R6,ON,CANADA

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 02期

关键词：

D O I：

10.1021/ic00080a026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tris((2-pyridyl)methyl)amine forms complexes with sodium and lithium ions. The enthalpy of formation of the lithium iodide complex in deuterioacetone was found to be 8.0 +/- 0.3 kcal/mol from proton resonance spectroscopic determination of exchange rates as a function of temperature. The complex crystallizes in the monoclinic space group P2(1)/c with a = 13.077(4) Angstrom, b = 12.221(11) Angstrom, c = 26.613(7) Angstrom, and beta = 94.642(24)degrees, with Z = 4;and R(w) = 0.083. Tris(2-(2-pyridyl)ethyl)amine forms a weaker complex with lithium ions but does not complex sodium ions. Theoretical calculations of the structure of the lithium complex were in good agreement with the results of the X-ray structure determination.

引用

页码：354 / 358

页数：5

共 23 条

[1] PYRIDINE DERIVATIVES AS COMPLEX FORMERS .8. PRODUCTION OF A NEW 4 AND A NEW 6 TOOTH LIGAND
ANDEREGG, G
WENK, F
[J]. HELVETICA CHIMICA ACTA, 1967, 50 (08) : 2330 - &
[2] ANDEREGG G, 1967, HELV CHIM ACTA, V50, P243
[3] X-RAY CRYSTAL-STRUCTURES OF SOME LITHIUM ARYL THIOLATES - MONOMERIC [ORTHO-MEC6H4SLI-(NC5H5)3], CHAIN [PHSLI.(NC5H5)2]-INFINITY, AND THE UNIQUE FOLDED LADDER OF [PHCH2SLI.NC5H5]-INFINITY WITH LI-S RUNGS
BANISTER, AJ
CLEGG, W
GILL, WR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (11) : 850 - 852
[4] THE SYNTHESES AND CRYSTAL-STRUCTURES OF 2 IMINOLITHIUM ADDUCTS - (PH2C=NLI.NC5H5)4, A TETRAMERIC PSEUDO-CUBANE FORMED BY STACKING 2 (LIN)2 4-MEMBERED RINGS, AND [BUT2C=NLI.OP(NME2)3]2, A DIMER PREVENTED STERICALLY FROM STACKING
BARR, D
SNAITH, R
CLEGG, W
MULVEY, RE
WADE, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (09): : 2141 - 2147
[5] BROAD-BAND HOMONUCLEAR DECOUPLING IN HETERONUCLEAR SHIFT CORRELATION NMR-SPECTROSCOPY
BAX, A
[J]. JOURNAL OF MAGNETIC RESONANCE, 1983, 53 (03) : 517 - 520
[6] INTERMOLECULAR FLUORINE EXCHANGE BETWEEN TETRABUTYLAMMONIUM HEXAFLUOROPHOSPHATE AND BF3 OR PF5
BROWNSTEIN, S
BORNAIS, J
[J]. CANADIAN JOURNAL OF CHEMISTRY-BACK YEAR, 1968, 46 (02): : 225 - +
[7] FORMATION AND EXCHANGE RATES OF SOME COMPLEXES OF BORON FLUORIDE WITH AMINES AND ETHERS
BROWNSTEIN, S
EASTHAM, AM
LATREMOUILLE, GA
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1963, 67 (05) : 1028 - &
[8] THE 1ST STABLE LITHIUM COMPLEX OF A PENTADENTATE MACROCYCLE INCORPORATING SP2-NITROGEN DONOR ATOMS ONLY - THE X-RAY CRYSTAL-STRUCTURE OF [LI(L2)(MEOH)][PF6] (L2 = 6,13-(BIS-2-HYDROXYETHYL)-6H,13H-TRIPYRIDO[CD,FG,LM] [1,2,4,7,9,10,13]HEPTA-AZAPENTADECINE)
CONSTABLE, EC
CHUNG, LY
LEWIS, J
RAITHBY, PR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (23) : 1719 - 1720
[9] DUPUIS M, 1980, NATIONAL RESOURCE CO
[10] DURANT F, 1967, ACTA CRYSTALLOGR, V22, P52

← 1 2 3 →