RUTHENIUM CARBONYL-COMPLEXES OF N-HETEROCYCLIC MOLECULES .2. PREPARATION, PROTONATION AND DECARBONYLATION REACTIONS OF COMPLEXES WITH A BIDENTATE TERPYRIDYL LIGAND - STRUCTURE OF [RU(CO)2(PHEN)(TPYH)](BF4)3

被引：39

作者：

THOMAS, NC ^{[1
]}

FISCHER, J ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,INST LE BEL,CRISTALLOCHEM CHIM STRUCT LAB,F-67070 STRASBOURG,FRANCE

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1990年 / 21卷 / 02期

关键词：

bidentate; carbonyl; complexes; decarbonylation; Ruthenium; terpyridyl;

D O I：

10.1080/00958979009409180

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes Ru(CO)2(CF3SO3)2(bidentate) {bidentate = 2, 2’-bipyridyl (bpy) or 1, 10-phenanthroline (phen)} react with 2, 2':6', 2''-terpyridyl (tpy) forming octahedral [Ru(CO)2(bidentate)(tpy)]2+compounds (II) which contain a bidentate tpy. Complex II (bidentate = phen) can be protonated to give [Ru(CO)2- (phen)(tpyH)](BF4)3the structure of which has been established by X-ray crystallography. Treatment of II with trimethylamine N-oxide in methanol at room temperature gives the monocarbonyl compounds [Ru(CO)(bidentate)(tpy)]2+(IV) which contain a tridentate tpy. Complex IV is also obtained by photolysis of II. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：119 / 128

页数：10

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