ELECTROSYNTHESIS, AN ALTERNATIVE FOR THE SYNTHESIS OF POLYCARBOSILANES

被引：22

作者：

BORDEAU, M

BIRAN, C

PONS, P

LEGER, MP

DUNOGUES, J

机构：

[1] Laboratoire de Chimie organique et organométallique (U.R.A., 35 CNRS), Université de Bordeaux I

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 382卷 / 03期

关键词：

D O I：

10.1016/0022-328X(90)80225-O

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The electrochemical reduction of chloromethyldimethylchlorosilane affords polycarbosilanes in high yields and this route constitutes a competitive route to 1,1,3,3-tetramethyl-1,3-disilacyclobutane formed in 34% crude yield. The solvent mixture was varied to yield its precursor, Cl(CH2SiMe2)2Cl, in 43% yield after distillation, while electrosynthesis in the presence of dimethyldichlorosilane provided bis(dimethyl-chlorosilyl)methane, another polycarbosilane precursor, in 60% yield after distillation. © 1990.

引用

页码：C21 / C24

页数：4

共 24 条

[1] NEW POLYCARBOSILANE MODELS .1. POLY[(METHYLCHLOROSILYLENE)METHYLENE], A NOVEL, FUNCTIONAL POLYCARBOSILANE [J].