ELECTRON IMPACT STUDIES .49. C13H9 SKELETAL-REARRANGEMENT FRAGMENT IN MASS SPECTRA OF BENZYL PHENYL KETONE DERIVATIVES

被引：19

作者：

BOWIE, JH

SIMONS, BK

DONAGHUE, PF

KALLURY, RKM

机构：

[1] Department of Organic Chemistry, University of Adelaide, Adelaide

来源：

TETRAHEDRON | 1969年 / 25卷 / 17期

关键词：

D O I：

10.1016/S0040-4020(01)82930-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The spectra of benzyl phenyl ketone derivatives contain ions at m/e 165 (C13H9) which are produced by skeletal-rearrangement processes. The rearrangement peak is most pronounced in the spectrum of the oxime of benzyl phenyl ketone where it arises mainly from an M-H2O species. Deuterium labelling studies and metastable characteristics are consistent with the M - 18 species having the properties of a 2.3-diphenyl-2-H-azirine molecular ion. © 1969.

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页码：3969 / +

页数：1

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