PERFLUOROALKYL DERIVATIVES OF SULPHUR .9. REACTION OF SULPHUR CHLORIDE PENTAFLUORIDE WITH TRIFLUOROETHYLENE

被引：20

作者：

BANKS, RE

HASZELDI.RN

MORTON, WD

机构：

[1] Chemistry Department, University of Manchester Institute of Science and Technology

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 15期

关键词：

D O I：

10.1039/j39690001947

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

U.v. irradiation of a mixture of sulphur chloride pentafluoride and trifluoroethylene yields a mixture (ca. 7:3) of 2-chloro-1,2,2- trifluoroethylsulphur pentafluoride (I) and 2-chloro-1,1,2-trifluoroethylsulphur pentafluoride (II). Both (I) and (II) give, inter alia, trifluoroethylene and chlorotrifluoroethylene when pyrolysed. Isomer (I) yields perfluorovinylsulphur pentafluoride when treated with potassium hydroxide, but isomer (II) appears to be completely destroyed by this reagent.

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页码：1947 / &

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