FACILE S-MONODEMETHYLATION OF 3,4,5-TRIS(METHYLTHIO)-1,2-DITHIOLIUM IODIDE - SYNTHESIS OF A HIGHLY FUNCTIONALIZED TETRATHIACYCLODECANE

被引：0

作者：

SINGH, JD ^{[1
]}

SINGH, HB ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,DEPT CHEM,BOMBAY 400076,INDIA

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 1993年 / 06期

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中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduction of 3,4,5-tris(methylthio)-1,2-dithiolium iodide (1) with sodium borohydride followed by oxidative work-up affords an isomeric mixture of the novel macrocycles 4,5,9,10-tetrakis(methylthio)-1,2,6,7-tetrathiacyclodeca-4,9-diene-3,8-dithione (6a) and 4,5,8,9-tetrakis(methylthio)-1,2,6,7-tetrathiacyclodeca-4,8-diene-3,10-dithione (6b).

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页码：224 / 225

页数：2

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