INFRARED DIODE-LASER SPECTROSCOPY OF THE ELECTRONIC GROUND-STATE OF GED (X2-PI-1/2)

被引：3

作者：

HUHN, G

SIMON, U

PETRI, M

ZIMMERMANN, W

URBAN, W

机构：

[1] Institut für Angewandte Physik der Universität Bonn, Bonn 1, Wegeierstraße 8

[2] Bayer AG, Leverkusen

来源：

MOLECULAR PHYSICS | 1992年 / 76卷 / 05期

关键词：

D O I：

10.1080/00268979200101841

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The fundamental and the first hot bands of the GeD radical in the X2-PI-1/2 state have been detected by tunable diode laser spectroscopy. Transitions from the five naturally occurring isotopes of germanium have been observed. Using an effective Hamiltonian, a set of molecular parameters for the X2-PI state was deter-mined using our data combined with those of Zimmermann et al. (1990, Molecular Physics, 70, 167). Values for the vibrational correction to the fine structure constant-alpha(A), the vibrational correction to the LAMBDA-type doubling constant-alpha(p+2q) and the spin-rotation constant-gamma were determined.

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页码：1029 / 1036

页数：8

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