ABNORMAL REACTIONS OF STERICALLY BULKY ORGANOMETALLICS ARM (AR=2,4,6-TRI-TERT-BUTYLPHENYL, M=LI OR MGBR) WITH LEAD DICHLORIDE

被引：13

作者：

OKAZAKI, R

SHIBATA, K

TOKITOH, N

机构：

[1] Department of Chemistry, Faculty of Science, The University of Tokyo, Hongo, Tokyo

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 45期

关键词：

PLUMBYLENE; PLUMBANE; DIPLUMBANE; X-RAY STRUCTURE ANALYSIS; SINGLE ELECTRON TRANSFER;

D O I：

10.1016/0040-4039(91)80232-U

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of ArLi (Ar: 2,4,6-tri-t-butylphenyl), generated from ArBr and n-BuLi, or ArMgBr with lead dichloride resulted in the formation of plumbane Ar'3PbBr, diplumbane (Ar'3Pb)2, and Ar'OH having a rear-ranged group Ar' (Ar': 2-(3,5-di-t-butylphenyl)-2-methylpropyl). The structure of Ar'3PbBr was established by X-ray crystallographic analysis.

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页码：6601 / 6604

页数：4

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