ASYMMETRIC SYNTHESIS OF ALPHA AMINOPHOSPHONIC ACIDS .4. ASYMMETRIC-SYNTHESIS OF ENANTIOMERICALLY PURE PHOSPHONIC ANALOGS OF GLUTAMIC-ACID AND PROLINE

被引：58

作者：

GROTH, U ^{[1
]}

RICHTER, L ^{[1
]}

SCHOLLKOPF, U ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ORGAN CHEM,TAMMANNSTR 2,W-3400 GOTTINGEN,GERMANY

来源：

TETRAHEDRON | 1992年 / 48卷 / 01期

关键词：

D O I：

10.1016/S0040-4020(01)80584-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Michael addition of the metallated camphor derivatives 2 to vinylogous esters and subsequential hydrolysis afforded phosphonic analogues of glutamic acid. The enantiomerically pure lactam 6 was reduced by LiBH4/BF3.OEt2 to phosphoproline 7.

引用

页码：117 / 122

页数：6

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