REGIOSELECTIVE FUNCTIONALIZATION OF CHIRAL NICKELACYCLES DERIVED FROM N-PROTECTED ASPARTIC AND GLUTAMIC ANHYDRIDES

被引：26

作者：

CASTANO, AM ^{[1
]}

ECHAVARREN, AM ^{[1
]}

机构：

[1] CSIC,INST QUIM ORGAN,JUAN CIERVA 3,E-28006 MADRID,SPAIN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 33期

关键词：

D O I：

10.1016/S0040-4039(00)97733-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The electrophilic cleavage of the nickelacycles resulting from oxidative addition of Ni(0) complexes to N-protected aspartic and glutamic anhydrides, followed by decarbonylation, gives rise regioselectively to derivatives of α-and β-alanine or α-and γ-aminobutyric acid, respectively. © 1990.

引用

页码：4783 / 4786

页数：4

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