REGIOSELECTIVE FUNCTIONALIZATION OF CHIRAL NICKELACYCLES DERIVED FROM N-PROTECTED ASPARTIC AND GLUTAMIC ANHYDRIDES

被引：26

作者：

CASTANO, AM ^{[1
]}

ECHAVARREN, AM ^{[1
]}

机构：

[1] CSIC,INST QUIM ORGAN,JUAN CIERVA 3,E-28006 MADRID,SPAIN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 33期

关键词：

D O I：

10.1016/S0040-4039(00)97733-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The electrophilic cleavage of the nickelacycles resulting from oxidative addition of Ni(0) complexes to N-protected aspartic and glutamic anhydrides, followed by decarbonylation, gives rise regioselectively to derivatives of α-and β-alanine or α-and γ-aminobutyric acid, respectively. © 1990.

引用

页码：4783 / 4786

页数：4

共 30 条

[1] CONVERSION OF SERINE TO STEREOCHEMICALLY PURE BETA-SUBSTITUTED ALPHA-AMINO-ACIDS VIA BETA-LACTONES
ARNOLD, LD
KALANTAR, TH
VEDERAS, JC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (24) : 7105 - 7109
[2] A NEW SYNTHETIC EQUIVALENT OF THE GLUTAMIC-ACID GAMMA-ANION AND ITS APPLICATION TO THE SYNTHESIS OF S-(+)-GAMMA-CARBOXYGLUTAMIC ACID
ATTWOOD, MR
CARR, MG
JORDAN, S
[J]. TETRAHEDRON LETTERS, 1990, 31 (02) : 283 - 284
[3] ASYMMETRIC AMINO-ACID SYNTHESIS - PREPARATION OF THE BETA-ANION DERIVED FROM ASPARTIC-ACID
BALDWIN, JE
MOLONEY, MG
NORTH, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1989, (04): : 833 - 834
[4] NON-PROTEINOGENIC AMINO-ACID SYNTHESIS - THE BETA-ANION DERIVED FROM ASPARTIC-ACID, AND ITS APPLICATION TO ALPHA-AMINO-ACID SYNTHESIS
BALDWIN, JE
MOLONEY, MG
NORTH, M
[J]. TETRAHEDRON, 1989, 45 (19) : 6309 - 6318
[5] PROTON-EXCHANGE AND EPIMERIZATION OF CO(III) CHELATED AMINO-ACIDS VIA CARBANION INTERMEDIATES
BUCKINGHAM, DA
STEWART, I
SUTTON, PA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (02) : 845 - 854
[6] CHANG CC, 1982, J BIOL CHEM, V257, P3564
[7] ELMARINI A, 1989, B SOC CHIM FR, P554
[8] ENZYMATIC PREPARATION OF ALPHA-DEUTERATED AND BETA-DEUTERATED OR TRITIATED AMINO-ACIDS WITH L-METHIONINE GAMMA-LYASE
ESAKI, N
SAWADA, S
TANAKA, H
SODA, K
[J]. ANALYTICAL BIOCHEMISTRY, 1982, 119 (02) : 281 - 285
[9] STEREOCHEMISTRY OF CATABOLISM OF THE RNA BASE URACIL
GANI, D
YOUNG, DW
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1985, (07): : 1355 - 1362
[10] STEREOCHEMISTRY OF THE DIHYDROURACIL DEHYDROGENASE REACTION IN METABOLISM OF URACIL TO BETA-ALANINE
GANI, D
YOUNG, DW
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (10) : 576 - 578

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