COORDINATION-COMPLEXES OF METAL-HALIDES WITH SUBSTITUTED 4-NITROSOANILINES

被引：7

作者：

CAMERON, M

GOWENLOCK, BG

VASAPOLLO, G

机构：

[1] POLITECN BARI,CTR MISO,CNR,IST CHIM,I-70126 BARI,ITALY

[2] HERIOT WATT UNIV,DEPT CHEM,EDINBURGH EH14 4AS,MIDLOTHIAN,SCOTLAND

来源：

POLYHEDRON | 1994年 / 13卷 / 09期

关键词：

D O I：

10.1016/S0277-5387(00)81703-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of substituted p-nitrosoanilines with metal halides have been prepared and studied by solid state CP/MAS NMR spectroscopy. The C-13 and N-15 NMR spectra give information concerning the structural changes that occur in the C-nitrosoligand on coordination to metals. Supplementary information is provided in some cases by Sn-119 and Cd-113 NMR spectra and also by Mossbauer spectroscopy for Sn complexes. It is shown that it is not possible to distinguish between sigma(N) and sigma(O) coordination on the basis of IR spectroscopy.

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页码：1371 / 1377

页数：7

相关论文

共 28 条

[1] SOLID-STATE CD-113 NMR-STUDIES ON CADMIUM COMPLEXES WITH GLYCINE, L-ALANINE, AND L-CYSTEINE [J].

BARRIE, PJ ;

GYANI, A ;

MOTEVALLI, M ;

OBRIEN, P .

INORGANIC CHEMISTRY, 1993, 32 (18) :3862-3867

[2] COORDINATION-COMPLEXES OF C-NITROSO COMPOUNDS - A C-13 NMR-STUDY OF SOME COMPLEXES OF PLATINUM WITH C-NITROSO COMPOUNDS [J].

BOYD, ASF ;

BROWNE, G ;

GOWENLOCK, BG ;

MCKENNA, P .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 345 (1-2) :217-220

[3] COORDINATION CHEMISTRY OF C-NITROSO-COMPOUNDS [J].

CAMERON, M ;

GOWENLOCK, BG ;

VASAPOLLO, G .

CHEMICAL SOCIETY REVIEWS, 1990, 19 (04) :355-379

[4] CORRELATION OF NO STRETCHING FREQUENCIES WITH COORDINATION MODES IN METAL-COMPLEXES OF C-NITROSO COMPOUNDS [J].

CAMERON, M ;

GOWENLOCK, BG ;

VASAPOLLO, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 378 (03) :493-496

[5]

CAMERON M, IN PRESS J ORGANOMET

[6] SN-119 NMR-STUDIES ON SOME ADDUCTS OF TIN(IV) HALIDES [J].

COLTON, R ;

DAKTERNIEKS, D .

INORGANICA CHIMICA ACTA-ARTICLES, 1983, 71 (MAY) :101-107

[7] URANYL COMPLEXES WITH PARA-NITROSO-N,N-DIMETHYLANILINE [J].

CONDORELLI, G ;

FRAGALA, I ;

GIUFFRIDA, S .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1975, 37 (05) :1177-1179

[8]

CONDORELLI G, 1966, B SEDUTE ACCAD GIOEN, V8, P791

[9] CRYSTAL-STRUCTURE OF N,N-DIMETHYL-PARA-NITROSOANILINE HYDROCHLORIDE HYDRATE [J].

DRANGFELT, O ;

ROMMING, C .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1974, A 28 (10) :1101-1105

[10]

GOWENLOCK BG, 1994, IN PRESS CAN J CHEM, V72