SYNTHESIS OF PYRROLIZIDINES USING AMINYL RADICALS GENERATED FROM SULFENAMIDE PRECURSORS

被引：49
作者：
BOWMAN, WR
CLARK, DN
MARMON, RJ
机构：
[1] Department of Chemistry, University of Technology, Loughborough,
来源：
TETRAHEDRON | 1994年 / 50卷 / 04期
关键词：
SULFENAMIDES; AMINYL RADICALS; PYRROLIZIDINES; TRIBUTYLTIN HYDRIDE; TANDEM RADICAL-CYCLIZATION;
D O I：
10.1016/S0040-4020(01)80838-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Tandem radical cyclisations of aminyl radicals generated from sulfenamide precursors have been used for the synthesis of pyrrolizidines and other polycyclic nitrogen heterocycles. The aminyl radicals are generated by reaction between sulfenamide precursors and Bu(3)SnH.
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页码：1295 / 1310
页数：16
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