A NEW ISOMER OF THE CIS-[CO(CYCLEN)CL-2](+) CATION (CYCLEN=1,4,7,10-TETRAAZACYCLODODECANE)

被引:18
作者
CASTILLOBLUM, SE [1 ]
SOSATORRES, ME [1 ]
机构
[1] UNIV NACL AUTONOMA MEXICO,FAC QUIM,DIV ESTUDIOS POSGRADO,COYOACAN 04510,DF,MEXICO
关键词
D O I
10.1016/0277-5387(94)00245-A
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This work describes the preparation of a new complex, 1, and its perchlorate salt 2 when cyclen (1,4,7,10-tetraazacyclododecane) and CoCl2.6H(2)O are reacted in anhydrous methanol. H-1 and C-13 NMR spectroscopies were used to determine the absolute configuration of the new coordination compound.
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页码:223 / 229
页数:7
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