PREPARATION AND SOME REACTIONS OF IRONTRICARBONYL COMPLEX OF THEBAINE

被引:21
作者
BIRCH, AJ
FITTON, H
机构
[1] Chemistry Department, Manchester University, Manchester
基金
澳大利亚研究理事会;
关键词
D O I
10.1071/CH9690971
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The methoxycyclohexadiene ring of thebaine readily complexes with Fe(CO)3, to give (I; R = Me). This group alters the reactivity of the thebaine molecule in a number of ways, protecting the diene system and permitting ready fission of the cyclic ether to give either reduced compounds, or carbonium salts such as (X), which undergo a novel rearrangement. © 1969, CSIRO. All rights reserved.
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页码:971 / &
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