PREPARATION AND SOME REACTIONS OF IRONTRICARBONYL COMPLEX OF THEBAINE

被引：21

作者：

BIRCH, AJ

FITTON, H

机构：

[1] Chemistry Department, Manchester University, Manchester

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 05期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1071/CH9690971

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The methoxycyclohexadiene ring of thebaine readily complexes with Fe(CO)3, to give (I; R = Me). This group alters the reactivity of the thebaine molecule in a number of ways, protecting the diene system and permitting ready fission of the cyclic ether to give either reduced compounds, or carbonium salts such as (X), which undergo a novel rearrangement. © 1969, CSIRO. All rights reserved.

引用

页码：971 / &

共 6 条

[1] NOVEL ANALGESICS AND MOLECULAR REARRANGEMENTS IN MORPHINE-THEBAINE GROUP .3. ALCOHOLS OF 6,14-ENDO-ETHENOTETRAHYDROORIPAVINE SERIES AND DERIVED ANALOGS OF N-ALLYLNORMORPHINE AND -NORCODEINE [J].